Table 3.

Parameters involved in isothermal and TASF simulations.

Parameter	Determination	Value
ts		0.5 min
Vinj		45-1050 nL (See Table S2)
F		3 μL/min
Tf		5 °C
Tsep		60 °C
van‘t Hoff Plot Slope	Experiment	See Table 2
van‘t Hoff Plot Intercept
Dm (310 K)	Literature[40,62]	See Table S1
η(T)	Literature[63,64]	See Eq. S2
∈ tot	Literature [65]	0.537
A		20
B		4.5
C	Literature [55]	0.01
D		0.42
n		1
dp		1.7 μm
L		6.0 cm
φ		0.2
${\sigma }_{t,\mathit{void},\mathit{iso}}^2$	Experiment	0.000571 min2
dpost col		25 μm
lpost col		25 cm