Table 3. Temperature Dependence on the KIEs of the HAT Reactions from p-OMe-DTBP to [(DMM-tmpa)CuII(O2•–)]+ (2).
kH (M–1 s–1) | kD (M–1 s–1) | kH/kD | |
---|---|---|---|
173 K | 11 | 1.0 | 11 |
178 K | 14 | 1.2 | 12 |
183 K | 23 | 2.1 | 11 |
188 K | 26 | 2.7 | 10 |
kH (M–1 s–1) | kD (M–1 s–1) | kH/kD | |
---|---|---|---|
173 K | 11 | 1.0 | 11 |
178 K | 14 | 1.2 | 12 |
183 K | 23 | 2.1 | 11 |
188 K | 26 | 2.7 | 10 |