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. 2014 Jun 22;136(28):9925–9937. doi: 10.1021/ja503105b

Table 3. Temperature Dependence on the KIEs of the HAT Reactions from p-OMe-DTBP to [(DMM-tmpa)CuII(O2•–)]+ (2).

  kH (M–1 s–1) kD (M–1 s–1) kH/kD
173 K 11 1.0 11
178 K 14 1.2 12
183 K 23 2.1 11
188 K 26 2.7 10