Table 2.

Pd-Catalyzed Carboamination of N-Allyl Sulfamides ^[a]

Entry	R	R1	R2	Product	Yield (%)[b]
1	Bn	Bn	p-Me-C6H4	2c	85
2	Bn	Bn	p-NC-C6H4	2a	90
3	Bn	Bn	p-MeO-C6H4	2d	90
4	Bn	Bn	o-Me-C6H4	2e	85
5	Bn	Bn	1-cyclohexenyl	2f	87[c]
6	Bn	Bn	E-1-decenyl[e]	2g	80[d,e,f]
7	Me	Bn	p-Cl-C6H4	2h	79
8	Bn	PMB	p-Me-C6H4	2i	90
9	Bn	Me	m-F3C-C6H4	2j	86
10	Bn	tBu	p-MeO-C6H4	2k	92
11	Bn	PMP	Ph	2l	90[g]
12	Me	Bn		2m	84
13	tBu	Bn	m-F3C-C6H4	2n	88[h]
14	H	allyl	Ph	2o	51[i]

^[a]Reaction Conditions: 1.0 equiv 1, 1.2 equiv R²OTf, 1.4 equiv LiO^tBu, 2 mol % Pd(OAc)₂, 5 mol % RuPhos, PhCF₃ (0.25 M), 100 ^°C.

^[b]Isolated yield (average of two experiments).

^[c]The reaction was conducted using Brettphos as ligand.

^[d]The reaction was conducted using ^tBu-Davephos as ligand.

^[e]The alkenyl triflate was used as a 5:1 mixture of E:Z isomers, and the product was obtained as a 5:1 E:Z mixture.

^[f]The reaction was conducted using 1.4 equiv R²OTf and 1.6 equiv LiO^tBu.

^[g]The reaction was conducted using ^tBu-X-Phos as ligand.

^[h]The reaction was conducted using 7.5 mol % ligand.

^[i]The reaction was conducted using 2.4 equiv R²OTf and 2.4 equiv LiO^tBu.