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. 2014 Jun 17;136(27):9528–9531. doi: 10.1021/ja502482a

Table 1. Polymers Generated via OCN-Mediated Radical Polymerization.

pol monomer [3]0/[1 or 2]0a xb yb zb Mnc PDIc
9 1 – 19 – – 26.3 1.17
10 1 and 3 1/3 30 9 – 23.9 1.22
11 2 and 3 1/6 – 7 42 23.0 1.17
a

Initial ratio of cross-linker [3]0 to ligand [1 or 2]0.

b

Cross-linker and ligand content in the resulting polymer were estimated by 1H NMR (see SI for details).

c

Mn in kDa and PDI values were determined by SEC-MALS.