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. Author manuscript; available in PMC: 2014 Jul 22.
Published in final edited form as: J Am Chem Soc. 2008 Jul 1;130(30):9836–9843. doi: 10.1021/ja801662y

Scheme 1.

Scheme 1

Monomer Synthesisa

a The hydrophobic component of the facially amphiphilic monomer is introduced in the second reaction step (R = methyl, ethyl, propyl, butyl, isopentyl, or hexyl), and the protected hydrophilic moiety is attached in the last step.