. 2014 Jun 30;79(14):6410–6418. doi: 10.1021/jo501157s

Table 1. Experimental Second-Order Rate Constants for the Reaction of Benzyl and 6-Methylfulvenyl Chlorides with Potassium Iodide in Acetone at Room Temperature^a.

substrate	k (M^–1 s^–1)
benzyl chloride^b	1.5 × 10^–3
6-chloromethyl-6-methylfulvene (1)	4.0 × 10^–2

Approximately 23 °C. Reactions were run under pseudo-first-order conditions: [substrate]₀ = 0.20 M and [KI]₀ = 0.01 M. The rate of appearance of product was monitored by ¹HNMR.

Conant, J. B.; Kirner, W. R. J. Am. Chem. Soc.1924, 46, 232–252. Lit. 2.15 × 10^–3 M^–1 s^–1 at 25 °C using a titrimetric method.

Table 1. Experimental Second-Order Rate Constants for the Reaction of Benzyl and 6-Methylfulvenyl Chlorides with Potassium Iodide in Acetone at Room Temperaturea.

Table 1. Experimental Second-Order Rate Constants for the Reaction of Benzyl and 6-Methylfulvenyl Chlorides with Potassium Iodide in Acetone at Room Temperature^a.