Table 2.
analyte, 40 pmol |
reflectron mode |
laser energya |
analyte signal intensity in arbitrary unitsb |
||||
---|---|---|---|---|---|---|---|
DHBB | ImDHB | ImCHCA | PyCHCA | CHCAB | |||
SOS | positive | low | – | – | 200, 940 | – | 100, 120 |
high | 240, 600 | 100, 130 | 340, 1450 | – | 140, 160 | ||
SOS | negative | low | – | – | 360, 1600 | – | 400, 760 |
high | 230, 1480 | 300, 380 | 1690, 2160 | – | 200, 540 | ||
Arixtra | positive | low | – | – | 100, 170 | – | – |
high | 100, 950 | – | – | – | – | ||
Arixtra | negative | low | – | – | 470, 560 | – | – |
high | 1200, 2050 | 100, 160 | 810, 1180 | – | 100, 140 |
Low-energy setting corresponded to the 10% transmission, and high-energy setting corresponded to the 25% transmission of the laser energy.
Signal intensity values are reported for [M + Na]+ and [M − Na]− SOS ions, and [M + Na − 2NaSO3 + 2H]+ and [M − Na − 2NaSO3 + 2H]− ions of Arixtra; absence of an analyte signal is denoted (−).