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. Author manuscript; available in PMC: 2014 Jul 29.
Published in final edited form as: Anal Chem. 2006 Mar 15;78(6):1774–1779. doi: 10.1021/ac051121q

Table 2.

Efficiency of the Tested ILMs for the UV-MALDI-TOF Detection of Two Model Analytes, SOS and Arixtra

analyte,
40 pmol
reflectron
mode
laser
energya
analyte signal intensity in arbitrary unitsb
DHBB ImDHB ImCHCA PyCHCA CHCAB
SOS positive low 200, 940 100, 120
high 240, 600 100, 130 340, 1450 140, 160
SOS negative low 360, 1600 400, 760
high 230, 1480 300, 380 1690, 2160 200, 540
Arixtra positive low 100, 170
high 100, 950
Arixtra negative low 470, 560
high 1200, 2050 100, 160 810, 1180 100, 140
a

Low-energy setting corresponded to the 10% transmission, and high-energy setting corresponded to the 25% transmission of the laser energy.

b

Signal intensity values are reported for [M + Na]+ and [M − Na] SOS ions, and [M + Na − 2NaSO3 + 2H]+ and [M − Na − 2NaSO3 + 2H] ions of Arixtra; absence of an analyte signal is denoted (−).