Table 1. Nitric Oxide Release from Polyurethane Coatings Doped with NO-Releasing MPTMS-RSNO and MAP3/NO Nanoparticles.
NO-release merits | MPTMS-RSNO | MAP3/NO |
---|---|---|
[NO]max (pmol cm–2 s–1) | 551.4 ± 130.0 | 685.8 ± 11.4 |
tmax (min)a | 1.68 ± 0.20 | 23.80 ± 7.17 |
t1/2 (h)b | 6.29 ± 2.07 | 0.93 ± 0.17 |
[NO]8h (pmol cm–2 s–1) | 14.0 ± 3.9 | 13.0 ± 3.2 |
[NO]12h (pmol cm–2 s–1) | 9.8 ± 3.8 | 3.7 ± 1.5 |
[NO]24h (pmol cm–2 s–1) | 3.3 ± 0.2 | 0c |
[NO]48h (pmol cm–2 s–1) | 1.0 ± 0.1 | 0c |
[NO]72h (pmol cm–2 s–1) | 0.5 ± 0.0 | 0c |
[NO]168h (pmol cm–2 s–1) | 0.5 ± 0.0 | 0c |
[NO]T (μmol cm–2)d | 3.14 ± 0.26e | 3.11 ± 0.27 |
td (h)f | 74.6 ± 16.6 | 16.0 ± 4.4 |
Time required to reach maximum NO flux.
Half-life for NO-release from PU films.
Nitric oxide release was below the limit of detection of the NOA.
Total amount of NO released.
Measured by irradiation of the sample flask with 200 W light.
Determined at the time at which 99% of the total NO was released.