TABLE 6.
Concentration (mean ± SD) of nitrated-PAHs in standard reference materials and urban air samples (Bamford et al., 2003)
| Urban air particulate concentration (ng/g) |
Diesel exhaust particulate concentration (ng/g) |
|||||
|---|---|---|---|---|---|---|
| Nitrated PAH | SRM 1648 | SRM 1649a | PM2.5 (Baltimore) | SRM 2975 | SRM 1975 | SRM 1650a |
| 1-Nitronaphthalene | 9.3±0.4 | 6.8±0.3 | 8.2±0.3 | 42.1±2.7 | 13.6±0.5 | 86.4±2.3 |
| 2-Nitronaphthalene | 7.9±0.4 | 10.0±0.5 | 7.1±0.2 | 124±4 | 37.1±0.9 | 238±3 |
| 2-Nitrobiphenyl | <5 | <5 | <5 | <7 | <7 | 15.3±3.7 |
| 3-Nitrobiphenyl | 4.4±0.1 | 3.6±0.5 | 2.5±0.3 | <7 | <7 | 58.1±1.6 |
| 5-Nitroacenaphthene | 3.6±0.4 | 3.1±0.3 | 1.7±0.2 | <10 | <10 | 37.0±2.9 |
| 2-Nitrofluorene | <2 | <2 | <2 | <2 | <2 | 46.2±2.6 |
| 9-Nitroanthracene | 134±9 | 359±0.6 | 123±5 | 2928±63 | 1284±16 | 6080±190 |
| 9-Nitrophenanthrene | 2.8±0.2 | 1.7±0.1 | 8.9±0.5 | 454±20 | 205±5 | 510±9 |
| 4-Nitrophenanthrene | 1.0±0.2 | 0.47± 0.03 | 0.59±0.03 | 25.4±1.0 | 10.8±1.4 | 150±4 |
| 3-Nitrophenanthrene | 23.7±2.3 | 22.0±0.6 | 16.0±0.4 | 189±15 | 80.3±4.1 | 4350±230 |
| 1-Nitrofluoranthene | <2 | <2 | <2 | 133±10 | 48.4±6.3 | 274±12 |
| 7-Nitrofluoranthene | <2 | <2 | <2 | <2 | <2 | <2 |
| 2-Nitrofluoranthene | 246±10 | 282±31 | 339±17 | 188±8 | 71±3 | 201±12 |
| 3-Nitrofluoranthene | 6.4±1.5 | 4.5±1.8 | 2.6±0.3 | 4301±330 | 1624±22 | 65.2±7.4 |
| 4-Nitropyrene | 9.1±0.7 | 5.5±0.6 | 8.8±1.2 | 173±11 | 68.2±2.4 | 135±8 |
| 8-Nitrofluoranthene | 13.0±2.1 | 8.8±1.4 | 5.6±0.6 | 656±46 | 220±6 | 106±17 |
| 1-Nitropyrene | 155±29 | 71.5±5.1 | 196±3 | 39, 640±1700 | 16, 070±590 | 18, 330±340 |
| 2-Nitropyrene | 48.9±2.4 | 24.4±4.0 | 35.5±5.8 | <4 | <4 | <4 |
| 7-Nitrobenz[a]anthracene | 43.0±4.3 | 351±3.6 | 351±2.9 | 5300±380 | 1962±70 | 995±68 |
| 6-Nitrochrysene | 6.9±0.6 | 4.4±0.2 | 2.0±0.2 | 2368±70 | 900±15 | 44.4±3.4 |
| 6-Nitrobenzo[a]pyrene | 61.0±8.7 | <40 | 309±37 | 1650±35 | 514±24 | 1442±47 |
| l-Nitrobenzo[e]pyrene | <7 | <7 | <7 | 1788±45 | 670±17 | <10 |
| 3-Nitrobenzo[e]pyrene | <5 | <5 | <5 | 6857±210 | 1825±71 | 89±19 |
| 1-Nitrobenzo[a]pyrene | <5 | <5 | <5 | <5 | <5 | <5 |
| 3-Nitrobenzo[a]pyrene | <5 | <5 | <5 | <5 | <5 | <5 |
| 1,3-Dinltropyrene | <2 | <2 | <2 | 1146±60 | 538±40 | 44 : 4±8 : 5 |
| 1,6-Dinitropyrene | <4 | <4 | <4 | 2543±220 | 934±14 | 84 : 5±6 : 2 |
| 1,8-Dinitropyrene | <2 | <2 | <2 | 3580±160 | 1377±43 | <9 |
Bold type highlights those substances that are potentially useful biomarkers of diesel exhaust exposure.