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. Author manuscript; available in PMC: 2014 Aug 15.
Published in final edited form as: J Am Chem Soc. 2013 Jul 31;135(32):12032–12037. doi: 10.1021/ja405394v

Scheme 4. Mechanistic Experiments for C-O Functionalization.

Scheme 4

(a) Stoichiometric formation and functionalization of a π-allyl Pd intermediate (b) Functionalization of a preoxidized N-nosyl urea under Pd(0) conditions.