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. Author manuscript; available in PMC: 2014 Aug 15.
Published in final edited form as: J Am Chem Soc. 2013 Jul 31;135(32):12032–12037. doi: 10.1021/ja405394v

Scheme 5. Mechanistic Experiments for C–N Functionalization.

Scheme 5

(a) Terminal vs internal olefin functionalization under PdII/B catalysis (b) Overall kinetic profile of the terminal olefin and the internal olefin under the standard C–N functionalization conditions