Skip to main content
. Author manuscript; available in PMC: 2014 Aug 15.
Published in final edited form as: J Am Chem Soc. 2013 Jul 31;135(32):12032–12037. doi: 10.1021/ja405394v

Table 3.

PdII/B catalyzed allylic C–N bond formation

graphic file with name nihms511760u3.jpg
graphic file with name nihms511760t10.jpg graphic file with name nihms511760t11.jpg graphic file with name nihms511760t12.jpg
graphic file with name nihms511760t13.jpg graphic file with name nihms511760t14.jpg graphic file with name nihms511760t15.jpg
graphic file with name nihms511760t16.jpg graphic file with name nihms511760t17.jpg
a

Diastereoselectivities and C–N:C–O ratios were measured by 1H NMR of the crude reaction mixtures; >20:1 dr and >20:1 C–N:C–O unless otherwise noted.

b

14: 9.8:1 dr; 20: 7:1 dr; 21: 12:1 dr.

c

16: 10:1 C–N:C–O; 17: 10:1 C–N:C–O