Table 1. Overview of Analytical Standards and Summary of Results for Fungal Metabolites Used in This Study^a.

					rank of correct molecular formula
name	molecular formula of Mb	ion species	m/zmeasc	no. detected/ no. annotated	Id	IIe
3AcDON	C17H22O7	[M + H]+	339.1436	37/18	1	4
DIAS	C19H26O7	[M + Na]+	389.1571	28/2	1	1
HT-2	C22H32O8	[M + Na]+	447.1989	32/15	1	1
T-2	C24H34O9	[M + Na]+	489.2093	72/47	2	5
ZEN	C18H22O5	[M + H]+	319.1538	89/17	1	5
FB3	C34H59NO14	[M + H]+	706.4014	77/27	7	152
GRIS	C17H17O6Cl	[M + H]+	353.0782	57/13	1	19
STER	C18H12O6	[M + H]+	325.0703	33/12	1	11
FB1	C34H59NO15	[M + H]+	722.3960	61/15	4	74
FB2	C34H59NO14	[M + H]+	706.4015	61/15	10	180

^aThe number of initially measured fragment signals (“detected”) in the ¹²C derived LC-MS/MS spectrum vs the number of annotated fragments automatically found by FragExtract. The rank indicates the correct elemental formula for the precursor ions (sorted by mass deviation in ppm) calculated with Xcalibur Software (version 2.1.0.1139), which allows a max of 400 possible molecular formulas. Seven allowed elements: C, H, N, O, Cl, S, and P (for HT-2, T-2, and DIAS: additionally one Na). For standard concentration please refer to Experimental section.

^bM = intact neutral molecule of fungal metabolite.

^cm/z_meas = measured m/z value.

^dWith the restriction of carbon atom count.

^eWithout the restriction of carbon atom count.