Table 3. Enthalpy and entropy changes of the sheet ↔ turn transition of penetratin in DMPC/DMPG (8:7) membranes.
| Residue, P/L | ln Keq versus 1000/T | ΔH (kcal/mol) | ΔS (kcal/mol K) | |
|---|---|---|---|---|
|
| ||||
| Slope | Intercept | |||
| I3α, 1:15 | −7.52 | 25.1 | 14.9 | 0.050 |
| N9α, 1:15 | −7.07 | 24.8 | 14.0 | 0.049 |
| I3α, 1:30 | −6.79 | 24.1 | 13.5 | 0.048 |
| N9α, 1:30 | −7.20 | 25.8 | 14.3 | 0.051 |
| Mean | — | — | 14.2 | 0.050 |
The thermodynamic values are for 1 mol of peptide.