Table 1.
Entry | Reactant | Condition | Product | HRMS |
---|---|---|---|---|
1 | 25 | TEMPO (0.7 eq), BAIB (4 eq), CH3CN-H2O, rt, 16h | [M+H]+: 519.3119 | |
2 | 24 | RuCl3 (0.7 eq), NaIO4 (4 eq), CH3CN-CCl4-H2O, rt, 7h | [M+H]+: 350.1656 [M+H3O]+: 368.1762 |
|
3 | 20 (+21) | RuCl3 (0.7 eq), NaIO4 (4 eq), CH3CN-CCl4-H2O, 50 °C, 2days | [M+H]+: 494.2609 [M+H3O]+: 512.2742 |