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. 2014 Aug 13;4:6054. doi: 10.1038/srep06054

Figure 2.

Figure 2

(a) Infrared spectra of CuF2(H2O)2(3-chloropyridine) at 300 K and various pressures demonstrating the disappearance of the 125 cm−1 lattice mode through the 0.8 GPa transition. (b) Frequency versus pressure for the infrared active modes in panel (a). (c) Room temperature Raman spectra at the indicated pressures showing the disappearance of a shoulder around 1565 cm−1. (d) Frequency versus pressure for the Raman active modes in panel (c). The vertical grey line marks the critical pressure for the 0.8 GPa magnetic crossover.