Table 4.
Limits of detection and summary statistics for detected OP pesticides in house dust from 15 Salinas agricultural homes and 13 Oakland urban homes by collection time point (ng/g).a,b
Precursor OP compound | Dialkylphosphate breakdown product(s) | LOD (ng/g) | Homes | Collection time point | No. of homes sampled | % DF | Concentration in dust (ng/g)
|
|||
---|---|---|---|---|---|---|---|---|---|---|
p50 | p75 | p95 | Max | |||||||
Diazinon | DEP, DETP | 4 | Agricultural | 1 | 14 | 86 | 15 | 19 | 56 | 56 |
2 | 15 | 73 | 14 | 17 | 36 | 36 | ||||
Urban | 1 | 13 | 54 | 9 | 16 | 139 | 139 | |||
2 | 12 | 50 | 5 | 21 | 133 | 133 | ||||
Chlorpyrifos | DEP, DETP | 10 | Agricultural | 1 | 14 | 57 | 22 | 32 | 200 | 200 |
2 | 15 | 53 | 20 | 26 | 135 | 135 | ||||
Urban | 1 | 13 | 39 | <LOD | 35 | 56 | 56 | |||
2 | 12 | 33 | <LOD | 33 | 43 | 43 | ||||
Tetrachlorvinphos | DMP | 10 | Agricultural | 1 | 14 | 14 | <LOD | <LOD | 252 | 252 |
2 | 15 | 7 | <LOD | <LOD | 271 | 271 | ||||
Urban | 1 | 13 | 8 | <LOD | <LOD | 16 | 16 | |||
2 | 12 | 0 | — | — | — | — | ||||
Malathion | DMP, DMTP, DMDTP | 10 | Agricultural | 1 | 14 | 7 | <LOD | <LOD | 52 | 52 |
2 | 15 | 7 | <LOD | <LOD | 71 | 71 | ||||
Urban | 1 | 13 | 15 | <LOD | <LOD | 877 | 877 | |||
2 | 12 | 8 | <LOD | <LOD | 1,158 | 1,158 | ||||
Diazinon-oxonc | DEP | 4 | Agricultural | 1 | 14 | 0 | — | — | — | — |
2 | 15 | 0 | — | — | — | — | ||||
Urban | 1 | 13 | 8 | <LOD | <LOD | 5 | 5 | |||
2 | 12 | 0 | — | — | — | — |
Abbreviations: LOD, limit of detection; DF, detection frequency; “—”, statistic not reported when analyte was not detected.
Organophosphate (OP) pesticides not detected in any samples included: methidathion, methyl parathion, and phorate.
Number of samples analyzed for OP pesticides in each location was restricted to samples with adequate amount of dust volume remaining after initial analyses for DAPs: 29 samples from 15 Salinas agricultural homes and 25 samples from 13 urban homes. Summary statistics reported are for the number of samples at each collection.
One molecule of the OP pesticide diazinon can either breakdown into DETP and the specific metabolite, isopropyl-methyl-hydroxypyrimidine (IMHP), or it may undergo activation into diazinon-oxon subsequently breaking down into DEP and IMHP.