Table 2.
Experimental and theoretical collision cross sections (Å2) of the d(CG)n duplexes [92].
Theorya |
|||||
---|---|---|---|---|---|
Duplex | Expt | Globular | A-helix | B-helix | Z-helix |
[4mer + Na − 4H]3− | 352 |
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407 | 392 | 405 |
[6mer − 3H]3− | 430 |
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533 | 515 | 502 |
[8mer + Na − 5H]4− | 536, 667 |
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643 | 654 |
[10mer − 5H]5− | 718 | 640 |
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783 | 763 |
[14mer − 7H]7− | 1006 | ||||
[14mer − 9H]9− | 1013 | 850 |
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1034 | 1035 |
[14mer + NH4 − 8H]7− | 1011 | ||||
[18mer − 9H]9− | 1268 | ||||
[18mer − 11H]11− | 1272 | 991 |
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1221 | 1205 |
[18mer + NH4 − 10H]9− | 1265 |
The assigned structures from the theoretical modeling are enclosed in boxes.