Skip to main content
. Author manuscript; available in PMC: 2015 Sep 1.
Published in final edited form as: J Fluor Chem. 2014 Jun 13;164:39–42. doi: 10.1016/j.jfluchem.2014.06.005

Table 2.

Retention and Separation Descriptors of Chromatographic Methods*

5°C 25°C 45°C
Homo-pairing Hetero-pairing Homo-pairing Hetero-pairing Homo-pairing Hetero-pairing
Parameters F-Col
F-Sol
H-Col
H-Sol
F-Col
H-Sol
H-Col
F-Sol
F-Col
F-Sol
H-Col
H-Sol
F-Col
H-Sol
H-Col
F-Sol
F-Col
F-Sol
H-Col
H-Sol
F-Col
H-Sol
H-Col
F-Sol
Separation factor α1/2 1.05 1.00 1.05 1.06 1.03 1.05 1.06 1.08 1.03 1.05 1.07 1.08
Separation factor α2/3 1.00 1.00 1.00 1.04 1.02 1.04 1.04 1.05 1.02 1.04 1.05 1.06
Separation factor α3/4 1.00 1.00 1.00 1.03 1.02 1.00 1.03 1.04 1.02 1.03 1.04 1.05
Mean value µ(min) 11.60 8.11 14.60 14.93 9.97 8.58 12.70 13.07 8.68 7.62 11.11 12.42
Variance σ2(min2) 0.07 0.00 0.11 0.69 0.07 0.14 0.49 0.85 0.06 0.16 0.61 0.93
*

Solvents and columns: fluorocarbon column (F-Col, n-C8F17), hydrocarbon column (H-Col, n-C8H17), fluorinated solvent (F-Sol, CF3CH2OH), hydrogenated solvent (H-Sol, CH3CH2OH).