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(a) Plots of the formation of Acr=O during the photocatalytic oxygenation of AcrH2 under irradiation (λ > 480 nm) for an O2-saturated PhCN solution containing (TMP)MnIII(OH) (1.0 × 10–5 M) in the presence of 5 (red), 10 (green), 20 (blue), or 30 mM (black) of AcrH2 as a substrate at 298 K. (b) Plot of the initial reaction rate versus concentration of AcrH2.
