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(a) Transient absorption spectral changes (red after 10 ps, blue 50 ps, and black 3000 ps) after photoexcitation of (TMP)MnIII(OH) in PhCN. Decay time profiles of absorbance at 638 nm due to [(TMP)MnIII(OH)]* (5T1) (b) in N2-saturated PhCN and (c) in O2-saturated PhCN. Decay time profiles of absorbance due to [(TMP)MnIII(OH)]* (7T1) at λ = 565 nm under (d) N2 and (e) O2.
