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. 2014 Aug 4;16(16):4308–4311. doi: 10.1021/ol502023d

Table 1. Scope of Allyl Alcoholsa,b.

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a

Nitrile (0.3 mmol) and allylic alcohol (0.6 mmol) in 2 mL of DMSO under 1 atm of CO2.

b

Reaction at 90 °C in 0.5 mL of DMSO.

c

1:2.5 (cis/trans).

d

1:14.3 (cis/trans).

e

1:4.6 (cis/trans).

f

Reaction time 4 h.

g

Reaction time 19 h. 1:5.3 (cis/trans).

h

Reaction time 8 h; a 23% conversion in the control reaction was observed.

i

Reaction time 7 h.