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Conformational itineraries employed by mannosidases. a) 3S1→3H4≠→1C4 itinerary of GH47 inverting α-mannosidase. b) 1S5↔B2,5≠↔OS2 itinerary employed by retaining GH2 and GH38 β-mannosidases, inverting GH92 α-mannosidases and retaining GH26 and GH113 β-mannanases (X, Y = leaving group, enzyme carboxylate or OH).
