Table 2. Comparison of Averaged Bond Distances (Å) and Angles (deg).
a | [WIICl2(dppe)2]b | [WIIICl2(dppe)2][PF6] |
---|---|---|
W–Cl | 2.4228(8) | 2.3207(6) |
W–P | 2.5008(7) | 2.5518(5)c |
Cl–W–Cl | 173.65(4) | 180 |
P–W–Pd | 79.14(3) | 78.27(2)c |
Values are averaged, where possible, with uncertainty propagations determined according to the general formula for uncertainty in a function of several variables detailed in ref (60).
Data from ref (59).
Values involving the disordered dppe ligand were excluded from the averages.
Ligand bite angle.