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Rate constants of the reactions of amino acid hydroperoxides with CBA and ebselen
| Hydroperoxide | kROOH + CBA | kROOH + ebselen |
|---|---|---|
| m−1 s−1 | m−1 s−1 | |
| TyrOOH | 23.4 ± 0.5 | (1.11 ± 0.06) × 103 |
| HPAOOHa | 7.0 ± 0.1 | (1.07 ± 0.08) × 103 |
| TrpOOH | 11.4 ± 0.2 | (1.54 ± 0.05) × 103 |
| HisOOHb | 23.3 ± 0.7 | (1.05 ± 0.07) × 103 |
| H2O2 | 1.5 ± 0.2 | 35 ± 1 |
a HPA-derived hydroperoxide.
b Histidine-derived hydroperoxide.
