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Selected bond lengths [Å] and angles [°] for complexes 3a and 3d.
| 3a | 3b | ||
|---|---|---|---|
| Au(1)-P(1) | 2.2546(14) | Au(1)-P(1) | 2.259(3) |
| Au(1)- S(1) | 2.3000(16) | Au(1)- S(1) | 2.307(3) |
| Fe-C | 2.032(4)-2.063(5) | Fe-C | 2.025(15) -2.050(15) |
| S-C(41) | 1.783(6) | S-C(1) | 1.761(14) |
| P(1)-Au(1)-S(1) | 171.33(5) | P(1)-Au(1)-S(1) | 177.75(11) |
| C(14)-Fe(1)-C(14A) | 180.0(3) | C(14)-Fe(1)-(C14A) | 179.999(2) |
| C(41)-S(1)-Au(1) | 100.93(19) | C(1)-S(1)-Au(1) | 104.0(5) |
