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. Author manuscript; available in PMC: 2014 Aug 24.
Published in final edited form as: Phys Chem Chem Phys. 2013 Jun 4;15(27):11313–11326. doi: 10.1039/c3cp43787f

Fig. 9.

Fig. 9

Eliminating the effects of refractive broadening. The complex lineshape of an r⃗ = 1.8 nm (50 mM) GdCl3 sample (spectrum 3 of Fig. 4) is plotted as a dotted, red line and can be well described by accounting for the effects of refractive broadening in a simple calculation of the resonance (dashed, blue line). This allows the determination of the true width of the resonance from the susceptibility response, which is shown with the solid, green line and demonstrates how dramatically the refractive broadening artificially broadens the measured lineshape at high concentration.