Table 1.

Chemical Shift Values for Occidiofungin Derived from the ocfN Mutant MS14GG88^a

Unit	No.	δC	δH (JHNHα in Hz)
	2	52.71, CH	4.59
Asn1	2-NH		7.75 (12.1)
	3	39.91, CH2	2.62, 2.41
	4	-
	4-NH2		7.39, 6.93
	2	58.47, CH	4.66, 4.61
BHN1	2-NH		7.81, 7.9 (8.1, 12.1)
	3	75.01, C	3.98, 4.02
	3-OH		4.66
	4	-
	4-NH2		7.24
	2	43.88, CH2	2.34, 2.36
NAA2	3	47.25, CH	4.23
	3-NH		7.31, 7.34 (8.4, 11.4)
	4	41.57, CH2	1.39, 1.76
	5	66.36, CH	3.50
	6	76.07, CH	3.08
	7	79.61, CH	3.72
	8	33.19, CH2	1.54
	9–17	25.14–28.02, CH2	1.27
	18	16.94, CH3	0.86
	2	58.59, CH	4.07, 4.15
Ser3	2-NH		8.11, 8.14 (11.2, 8.0)
	3	70.23, 64.29	3.49, 3.45
	3-OH		4.95
	2	58.71,CH	4.06, 4.15
BHY4	2-NH		7.83, 7.94 (8.7, 11.7)
	3	73.75,CH	4.98, 5.08
	3-OH		5.66, 5.73
	4	-
	5,6	-	7.15
	8,9	-	6.67
	2	53.49, CH	4.43
DABA5	2-NH2		7.66 (8.5)
	3	32.68, CH2	1.88, 2.11
	4	39.17, CH2	2.92
	4, NH		7.71
	2	44.76, CH2	3.87, 3.58, 3.84, 3.70
Gly6	2-NH		7.68, 7.85
	2	53.25, CH	4.51, 4.58
Asn7	2-NH		8.35, 8.41 (9.3, 8.7)
	3	40.03, CH2	2.61, 2.38
	4	-
	4-NH2		7.39, 6.93
	2	58.11, CH	4.33, 4.32
Ser8	2-NH		7.76, 7.78 (8.2, 12.00)
	3	64.59	3.61, 3.62
	3-OH		4.79

^aProton chemical shift values are from a TOCSY and NOESY experiments. ¹³C values are from the HSQC experiment.