. Author manuscript; available in PMC: 2014 Aug 25.

Published in final edited form as: Anal Chem. 2011 Mar 10;83(7):2622–2630. doi: 10.1021/ac103013h

Table 1.

Analyte, precursor and productions, compound-dependent mass spec parameters^†, compound class* and internal standard used for quantification.

Analyte	Parent Ion (m/z)	Frag Ions (m/z)	C.E. (V)	C.X.P. (V)	D.P. (V)	F.P. (V)	Class	Internal Standard
Test	289	97	33	6	61	240	P	d₃ -Test
Test	289	109	35	18	61	240	P	d₃ -Test
d₃ -Test	292	97	33	6	61	240	IS	NA
d₃ -Test	292	109	35	18	61	240	IS	NA
Andro	287	97	34	16	104	282	P	d₃ -Test
Andro	287	109	34	5	104	282	P	d₃ -Test
Bold	287	121	31	8	70	265	P	d₃-Bold
Bold	287	135	19	12	70	265	P	d₃-Bold
d₃-Bold	290	121	33	22	70	265	IS	NA
d₃-Bold	290	138	23	7	70	265	IS	NA
5-Andro	289	187	27	16	101	210	M_Bold	d₃-Bold
5-Andro	289	69	43	12	101	210	M_Bold	d₃-Bold
Meta	301	149	21	8	51	180	P	d₃ -Test
Meta	301	121	35	6	51	180	P	d₃ -Test
6-Meta	317	281	18	18	56	250	M_Meta	d₃-Bold
6-Meta	317	299	13	18	56	250	M_Meta	d₃-Bold
Stan	329	81	71	14	66	220	P	NA
Stan	329	95	59	16	66	220	P	NA
d₃-Stan	332	81	76	14	159	301	IS	d₃-Stan
d₃-Stan	332	95	60	16	159	301	IS	d₃-Stan
16-Stan	345	81	73	14	71	240	M_Stan	d₃-Stan
16-Stan	345	95	61	16	71	240	M_Stan	d₃-Stan
Tren	271	253	30	16	58	268	P	d₃-Bold
Tren	271	199	33	16	58	268	P	d₃-Bold
Epi-Tren	271	253	30	16	58	268	M_Tren	d₃-Bold
Epi-Tren	271	199	33	16	58	268	M_Tren	d₃-Bold
Mete	303	83	35	14	51	230	P	d₃-Bold
Mete	303	187	29	16	51	230	P	d₃-Bold
CH₃-Test	303	97	37	16	56	240	P	d₃ -Test
CH₃-Test	303	109	35	18	56	240	P	d₃ -Test
Nan	275	109	37	18	66	180	P	d₃-Bold
Nan	275	257	17	42	66	180	P	d₃-Bold
Tetra	313	295	21	20	126	344	P	d₃-Bold
Tetra	313	241	31	14	126	344	P	d₃-Bold
Ox	307	289	17	24	86	340	P	d₃ -Test
Ox	307	271	19	26	86	340	P	d₃ -Test
Epi-Ox	307	289	17	24	86	340	M_OX	d₃-Bold
Epi-Ox	307	271	19	26	86	340	M_OX	d₃-Bold