Table 1.
Selected backbone torsion angles and sugar pucker data for 8β and 11β and related bi/tricyclo-nucleosides from X-ray structures.
γ | δ | χ | P | νmax | |
8β | 86.8° | 150.1° | −106.4° | 167.8° | 36.1 |
11β | 86.9° | 146.0° | −115.7° | 160.7° | 36.3 |
bc-Ta | 149.3° | 126.5° | −112.7° | 128.4° | 42.4 |
tc-Tb Mol A | 125.0° | 152.5° | −130.4° | 172.2° | 36.7 |
tc-Tb Mol B | 154.8° | 98.7° | −120.3° | 94.4° | 36.0 |
aRef [33]; btwo structurally independent molecules per asymmetric unit.