Table 3. Additives data from wine cellar jars.
| ARCHEM # | Jar # | Compounds of Interest | Possible Additive Source(s) | Absolute Abundance* | Relative Abundance (%)† | Ratio to Tartaric Acid‡ | Ratio to Syringic Acid‡ |
| 4324 | 1 | cinnamic acid | storax resin | 1494759 | 25.83 | 0.4470 | 7.3806 |
| 4296 | 2 | cinnamic acid | storax resin | 1276725 | 15.93 | 0.4249 | 5.3251 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 228932 | 2.86 | 0.0762 | 0.9549 | ||
| methyl syringate | honey | 158663 | 1.98 | 0.0528 | 0.6618 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 1614423 | 20.15 | 0.5373 | 6.7337 | ||
| cedrol | cedar oil | 2043677 | 25.50 | 0.6801 | 8.5241 | ||
| 4295 | 3 | cinnamic acid | storax resin | 5288827 | 24.17 | 0.3882 | 26.9371 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 97827 | 0.45 | 0.0072 | 0.4983 | ||
| methyl syringate | honey | 135629 | 0.62 | 0.0100 | 0.6908 | ||
| moronic Acid | pistacia resin | 4781078 | 21.85 | 0.3510 | 24.3510 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 143789 | 0.66 | 0.0106 | 0.7323 | ||
| masticadienoic acid | pistacia resin | 196814 | 0.90 | 0.0144 | 1.0024 | ||
| 4293 | 4 | moronic acid | pistacia resin | 2566950 | 19.14 | 0.3442 | 18.8781 |
| masticadienoic acid | pistacia resin | 157914 | 1.18 | 0.0212 | 1.1613 | ||
| 4323 | 5 | N/A | N/A | N/A | N/A | N/A | N/A |
| 4312 | 6 | cinnamic acid | storax resin | 41939 | 0.28 | 0.2887 | N/A |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 4251964 | 28.07 | 29.2692 | N/A | ||
| methyl syringate | honey | 539556 | 3.56 | 3.7141 | N/A | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 4528939 | 29.90 | 31.1758 | N/A | ||
| cedrol | cedar oil | 366042 | 2.42 | 2.5197 | N/A | ||
| 4304 | 7 | cineole | cyperus, mint, juniper berries, or cinnamon bark | 26747 | 2.14 | 0.0662 | 0.1174 |
| oleanoic acid | cyperus, pistacia resin, storax resin | 1239199 | 100 | 3.0650 | 5.4391 | ||
| cedrol | cedar oil | 121888 | 9.84 | 0.3015 | 0.5350 | ||
| 4307 | 8 | cinnamic acid | storax resin | 4379377 | 100 | 5.4354 | N/A |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 19364 | 0.44 | 0.0240 | N/A | ||
| methyl syringate | honey | 208538 | 4.76 | 0.2588 | N/A | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 390542 | 8.92 | 0.4847 | N/A | ||
| 4321 | 9 | cinnamic acid | storax resin | 2442191 | 23.65 | 0.2365 | 12.2398 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 573568 | 5.56 | 0.0556 | 2.8746 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 1018503 | 9.86 | 0.0986 | 5.1046 | ||
| cedrol | cedar oil | 196248 | 1.90 | 0.0190 | 0.9836 | ||
| 4291 | 11 | cinnamic acid | storax resin | 245035 | 0.89 | 0.0204 | 1.7075 |
| moronic acid | pistacia resin | 4975001 | 18.00 | 0.4151 | 34.6668 | ||
| masticadienoic acid | pistacia resin | 470967 | 1.70 | 0.0393 | 3.2818 | ||
| 4322 | 11 | cinnamic acid | storax resin | 2021760 | 7.43 | 0.0874 | 2.5425 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 96850 | 0.36 | 0.0042 | 0.1218 | ||
| methyl syringate | honey | 105724 | 0.39 | 0.0046 | 0.1330 | ||
| moronic acid | pistacia resin | 9005507 | 33.08 | 0.3891 | 11.3249 | ||
| masticadienoic acid | pistacia resin | 791283 | 2.91 | 0.0342 | 0.9951 | ||
| 4313 | 12 | cinnamic acid | storax resin | 7282 | 3.19 | 0.0319 | 2.3597 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 34235 | 14.99 | 0.1499 | 11.0936 | ||
| 4316 | 13 | cinnamic acid | storax resin | 19864640 | 100 | 11.0822 | N/A |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 2418428 | 12.17 | 1.3492 | N/A | ||
| methyl syringate | honey | 1206024 | 6.07 | 0.6728 | N/A | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 5158279 | 25.97 | 2.8777 | N/A | ||
| cedrol | cedar oil | 3763042 | 18.94 | 2.0994 | N/A | ||
| 4305 | 15 | cinnamic acid | storax resin | 28785576 | 53.19 | 12.5429 | 1.8623 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 3235294 | 5.98 | 1.4097 | 0.2093 | ||
| caryophyllene | cedar oil, mint, juniper berries, or cinnamon bark | 2652198 | 4.90 | 1.1557 | 0.1716 | ||
| methyl syringate | honey | 1289913 | 2.38 | 0.5621 | 0.0835 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 5544408 | 10.24 | 2.4159 | 0.3587 | ||
| cedrol | cedar oil | 7012114 | 12.96 | 3.0554 | 0.4536 | ||
| 4300 | 16 | cinnamic acid | storax resin | 555136 | 16.48 | 1.4170 | 0.7159 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 1250074 | 37.11 | 3.1908 | 1.6121 | ||
| methyl syringate | honey | 311317 | 9.24 | 0.7946 | 0.4015 | ||
| myrtenyl acetate | myrtle | 90137 | 2.68 | 0.2301 | 0.1162 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 2957384 | 87.80 | 7.5486 | 3.8138 | ||
| cedrol | cedar oil | 2898403 | 86.05 | 7.3981 | 3.7377 | ||
| 4299 | 17 | cinnamic acid | storax resin | 1162478 | 24.84 | 0.8915 | 2.8802 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 3030522 | 64.76 | 2.3242 | 7.5085 | ||
| methyl syringate | honey | 283333 | 6.05 | 0.2173 | 0.7020 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 2812546 | 60.10 | 2.1570 | 6.9684 | ||
| cedrol | cedar oil | 1838714 | 39.29 | 1.4102 | 4.5556 | ||
| 4311 | 18 | cinnamic acid | storax resin | 577577 | 9.98 | 0.3381 | 1.7616 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 5161095 | 89.14 | 3.0210 | 15.7412 | ||
| methyl syringate | honey | 965568 | 16.68 | 0.5652 | 2.9450 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 4619771 | 79.79 | 2.7041 | 14.0902 | ||
| cedrol | cedar oil | 1094098 | 18.90 | 0.6404 | 3.3370 | ||
| 4303 | 19 | cinnamic acid | storax resin | 53410 | 0.36 | 0.0945 | 0.0073 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 1712400 | 11.44 | 3.0314 | 0.2352 | ||
| caryophyllene | cedar oil, mint, juniper berries, or cinnamon bark | 766913 | 5.13 | 1.3576 | 0.1053 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 1987962 | 13.29 | 3.5192 | 0.2730 | ||
| cedrol | cedar oil | 735800 | 4.92 | 1.3026 | 0.1011 | ||
| 4302 | 20 | cinnamic acid | storax resin | 8975654 | 100 | 18.9433 | 30.1102 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 149823 | 16.49 | 0.3162 | 0.5026 | ||
| methyl syringate | honey | 155327 | 1.73 | 0.3278 | 0.5211 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 1613479 | 17.98 | 3.4053 | 5.4127 | ||
| cedrol | cedar oil | 440547 | 4.91 | 0.9298 | 1.4779 | ||
| 4297 | 22 | cinnamic acid | storax resin | 14466863 | 100 | 26.4827 | 3.1869 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 879020 | 6.08 | 1.6091 | 0.1936 | ||
| methyl syringate | honey | 144339 | 1.00 | 0.2642 | 0.0318 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 1913842 | 13.23 | 3.5034 | 0.4216 | ||
| cedrol | cedar oil | 898342 | 6.21 | 1.6445 | 0.1979 | ||
| 4306 | 23 | cinnamic acid | storax resin | 583336 | 19.38 | 0.7528 | 2.3230 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 1616217 | 53.68 | 2.0859 | 6.4362 | ||
| methyl syringate | honey | 160411 | 5.33 | 0.2070 | 0.6388 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 2465266 | 81.88 | 3.1816 | 9.8174 | ||
| cedrol | cedar oil | 1467052 | 48.73 | 1.8933 | 5.8422 | ||
| 4308 | 24 | cinnamic acid | storax resin | 88711 | 3.25 | 0.1013 | 0.2318 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 2416827 | 88.51 | 2.7604 | 6.3146 | ||
| methyl syringate | honey | 212555 | 7.78 | 0.2428 | 0.5554 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 2090629 | 76.56 | 2.3879 | 5.4624 | ||
| 4310 | 25 | cinnamic acid | storax resin | 8059 | 0.36 | .0107 | 0.0044 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 215071 | 9.49 | 0.2844 | 0.1183 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 2266978 | 100 | 2.9980 | 1.2471 | ||
| cedrol | cedar oil | 1281799 | 56.54 | 1.6952 | 0.7051 | ||
| 4298 | 26 | cinnamic acid | storax resin | 16405292 | 100 | 13.8041 | 42.6057 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 1974529 | 12.04 | 1.6615 | 5.1280 | ||
| methyl syringate | honey | 741031 | 4.52 | 0.6235 | 1.9245 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 3827611 | 23.33 | 3.2207 | 9.9406 | ||
| cedrol | cedar oil | 254127 | 15.53 | 0.2138 | 0.6600 | ||
| 4292 | 27 | cinnamic acid | storax resin | 243079 | 0.83 | 0.0345 | 0.4771 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 64891 | 0.22 | 0.0092 | 0.1274 | ||
| methyl syringate | honey | 104826 | 0.36 | 0.0149 | 0.2058 | ||
| moronic acid | pistacia resin | 5290463 | 18.03 | 0.7501 | 10.3847 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 105802 | 0.36 | 0.0150 | 0.2077 | ||
| masticadienoic acid | pistacia resin | 389893 | 1.33 | 0.0553 | 0.7653 | ||
| 4314 | 28 | cinnamic acid | storax resin | 1701520 | 19.30 | ||
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 3946414 | 44.76 | 2.1184 | 2.8204 | ||
| methyl syringate | honey | 1578962 | 17.91 | 0.8476 | 1.1284 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 7184739 | 81.48 | 3.8567 | 5.1347 | ||
| cedrol | cedar oil | 4705967 | 53.37 | 2.5261 | 3.3632 | ||
| 4320 | 29 | cinnamic acid | storax resin | 894407 | 4.19 | 0.2232 | 1.2573 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 105494 | 0.49 | 0.0263 | 0.1483 | ||
| caryophyllene | cedar oil, mint, juniper berries, or cinnamon bark | 234542 | 1.10 | 0.0585 | 0.3297 | ||
| methyl syringate | honey | 200929 | 0.94 | 0.0501 | 0.2825 | ||
| moronic acid | pistacia resin | 5538087 | 25.96 | 1.3817 | 7.7853 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 145885 | 0.68 | 0.0364 | 0.2051 | ||
| masticadienoic acid | pistacia resin | 465817 | 2.18 | 0.1162 | 0.6548 | ||
| 4301 | 31 | cinnamic acid | storax resin | 78383225 | 100 | 59.8162 | 123.3591 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 3412391 | 4.35 | 2.6041 | 5.3704 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 5089707 | 6.49 | 3.8841 | 8.0102 | ||
| cedrol | cedar oil | 3385811 | 4.32 | 2.5838 | 5.3286 | ||
| 4317 | 33 | cinnamic acid | storax resin | 2209658 | 43.96 | 0.4396 | 4.9602 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 280319 | 5.58 | 0.0558 | 0.6292 | ||
| caryophyllene | cedar oil, mint, juniper berries, or cinnamon bark | 107570 | 2.14 | 0.0214 | 0.2415 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 560737 | 11.16 | 0.1116 | 1.2587 | ||
| cedrol | cedar oil | 41459 | 0.82 | 0.0082 | 0.0931 | ||
| 4325 | 34 | cinnamic acid | storax resin | 537645 | 1.98 | 0.0995 | 2.6960 |
| methyl syringate | honey | 35184 | 0.13 | 0.0065 | 0.1764 | ||
| moronic acid | pistacia resin | 3838164 | 14.14 | 0.7105 | 19.2463 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 59010 | 0.22 | 0.0109 | 0.2959 | ||
| masticadienoic acid | pistacia resin | 303105 | 1.12 | 0.0561 | 1.5199 | ||
| 4319 | 35 | cinnamic acid | storax resin | 246579 | 33.68 | 0.5020 | 0.4576 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 295643 | 40.38 | 0.6018 | 0.5487 | ||
| caryophyllene | cedar oil, mint, juniper berries, or cinnamon bark | 46537 | 6.36 | 0.0947 | 0.0864 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 150258 | 20.52 | 0.3059 | 0.2789 | ||
| 4318 | 36 | cinnamic acid | storax resin | 2605220 | 8.05 | 0.3289 | 0.3513 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 3147852 | 9.73 | 0.3974 | 0.4245 | ||
| caryophyllene | cedar oil, mint, juniper berries, or cinnamon bark | 888008 | 2.75 | 0.1121 | 0.1197 | ||
| methyl syringate | honey | 240911 | 0.74 | 0.0304 | 0.0325 | ||
| moronic acid | pistacia resin | 8034511 | 24.84 | 1.0143 | 1.0835 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 238757 | 0.74 | 0.0301 | 0.0322 | ||
| masticadienoic acid | pistacia resin | 338245 | 1.05 | 0.0427 | 0.0456 | ||
| 4315 | 37 | cinnamic acid | storax resin | 1296918 | 21.27 | 1.3023 | 0.4644 |
| cineole | cyperus, mint, juniper berries, or cinnamon bark | 391683 | 6.42 | 0.3933 | 0.1403 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 2582576 | 42.35 | 2.5933 | 0.9248 | ||
| cedrol | cedar oil | 1654328 | 27.13 | 1.6612 | 0.5924 | ||
| 4289 | Base | cinnamic acid | storax resin | 6555436 | 21.19 | 1.8474 | 47.7589 |
| caryophyllene | cedar oil, mint, juniper berries, or cinnamon bark | 1308486 | 4.23 | 0.3688 | 9.5328 | ||
| methyl syringate | honey | 228195 | 0.74 | 0.0643 | 1.6625 | ||
| moronic acid | pistacia resin | 10566264 | 34.15 | 2.9777 | 76.9794 | ||
| oleanoic acid | cyperus, pistacia resin, storax resin | 207828 | 0.67 | 0.0586 | 1.5141 | ||
| masticadienoic acid | pistacia resin | 333968 | 1.08 | 0.0941 | 2.4331 |
*Peak area determined by integration in chromatograms.
†
Percentage relative to maximum peak in a given chromatogram.
‡
Ratio of compound of interest's absolute abundance to organic acid's absolute abundance.