Table 2.
Room-temperature Mössbauer parameters for as-received and acetylene-treated coal fly ash samples
| Values | |||||
|---|---|---|---|---|---|
| As-received |
SX1_U |
SX2_U |
SX3_U |
D1_U |
D2_U |
| Bhf (T) |
49.0 |
51.6 |
44.2 |
- |
- |
| δ (mm/s) |
0.40 |
0.45 |
0.59 |
0.45 |
0.79 |
| ΔEQ (mm/s) |
−0.02 |
−0.13 |
−0.01 |
0.95 |
2.33 |
| Area (%) |
21 |
18 |
27 |
23 |
11 |
| Treated |
SX1_T |
D1_T |
D2_T |
|
|
| Bhf (t) |
20.5 |
- |
- |
|
|
| δ (mm/s) |
0.29 |
0.43 |
1.02 |
|
|
| ΔEQ (mm/s) |
−0.003 |
0.41 |
2.15 |
|
|
| Area (%) | 49 | 21 | 30 | ||
The as-received sample showed that the total population of the oxides is 66% and 34% is attributed to silicates. After treatment, a decrease in the area fraction of 17% was observed for the oxides with a corresponding increase in the silicates.