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Synthesis of polyisoprenylated cysteinyl amide inhibitors (PCAIs) of PMPMease. Reagents: (a) −10°C, PBr3, Et2O (b) TEA, L-cysteine methyl ester, Anh. MeOH (c) 6-bromohexanoyl chloride, TEA, DCM, (d) K2CO3, amine, toluene, (e) amine, 90°C, ON.
