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. 2014 May 23;136(24):8766–8771. doi: 10.1021/ja503593n

Table 2. Impact of Sulfide Substituents on Sulfimidation Activity with P411BM3-CIS T438S.

graphic file with name ja-2014-03593n_0006.jpg

entry R1 in 7 R2 in 7 TTN 8 TTN 9
a -OMe -H 300 270
b -Me -H 190 400
c -H -Me 100 390
d -H -H 30 500
e -CHO -H <1a 510
a

Trace product observed by liquid chromatography-mass spectrometry (LC-MS).