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. Author manuscript; available in PMC: 2014 Sep 5.
Published in final edited form as: Chem Rev. 2013 Jun 17;113(8):5701–5765. doi: 10.1021/cr4000144

Table 8.

Rearrangement of Quincoridine-Derived 2-Iodomethyl-2-Azabicyclo[2.2.2]octanes via Bridged Iminium by Hoffmann

graphic file with name nihms495222t10.jpg
entry 369 R1 R2 AgX yield of
371 (%)
1 369a CH=CH2 H AgOBz 74
2 369b Et H AgOBz 62
3 369c O= AgOBz 72
4 369e C≡C-Ph H AgOBz 70