Table 2.
Parameters for relaxation of Trp synthase serine complexes9
| Positive P-jump
|
Negative P-jump
|
|||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Cation ligand | ko,s−1 | ΔVo‡ mL/mol−1 |
βo‡ mL/MPa−1 |
kc, s−1 | ΔVc‡ mL/mol−1 |
βo‡ mL/MPa−1 |
ko,s−1 | ΔVo‡ mL/mol−1 |
βo‡ mL/MPa−1 |
kc,s−1 | ΔVc‡ mL/mol−1 |
βo‡ mL/βoMPa−1 |
| Na+ | 1.09 | −12 | 0.397 | 17.3 | 125 | 0.397 | 0.34 | −48 | 0.230 | 5.45 | 89 | 0.229 |
| NH4+ | 0.014 | −127 | −0.588 | 47.5 | 36 | −0.630 | 0.0043 | −153 | −0.736 | 14.4 | 8 | −0.736 |
| Na+ | 0 (1.8 × 10−6) | −279 | −1.46 | 0.139 | −89 | −1.46 | 0 (2.0 × 10−8) | −235 | −1.32 | 0.0015 | −46 | −1.32 |
| BZIa | ||||||||||||
| 0 (3.9 × 10−8) | −349 | −1.84 | 0.003 | −160 | −1.84 | 0 (3.2 × 10−7) | −285 | −1.59 | 0.0247 | −96 | −1.59 | |
Values in parentheses are calculated on the basis of kc and Keq from Table 1.