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. Author manuscript; available in PMC: 2014 Sep 9.
Published in final edited form as: Macromol Biosci. 2014 Jun 6;14(9):1325–1336. doi: 10.1002/mabi.201400124

Table 1.

Results for PMLA esterification.

Solubility
Conversion
[%]		 Yield
[%]		 Mwa
[g mol−1]		 Ða) Tg
[°C]		 H2O DMSO CHCl3
PMLA – – 30000 1.2 110 + + −
coPMLA-Et50H50 56 62 33 000 (33 600) 2.4 31 − + −
PMLA-Et100 100 72 36 000 (37 200) 1.8 19 − + +
coPMLA-Bu50H50 53 57 34 000 (37 200) 2.6 13 − + −
PMLA-Bu100 100 53 41 000 (44 500) 2.3 −12 − + +
a

Weight-average molecular weights and dispersities determined by GPC. In parenthesis, values estimated on the basis of the attained esterification degree.