TABLE 6. Iodide and iodate Kd values after 21 days of composite sediments recovered from 200 West Area borehole cores (Santschi et al., 2012).
Composite sedimenta | Organic carbon (%) | Inorganic carbon (%) | Total sediment iodine (μg/g) | Total DOC (μM)b | Iodide, spiked Kd (mL/g)c | Iodate spiked Kd (mL/g)c |
---|---|---|---|---|---|---|
H3 | 0.15 | 0.18 | 2.10 | 94 ± 17 | 3.38 | 3.94 |
H1 | 0.12 | 0.92 | 4.79 | 284 ± 33 | 0.08 | 1.78 |
H2 | 0.04 | 0.01 | 0.68 | 0 | 0.00 | 0.83 |
a Sediment 1: composite of fine-grained sediments, mostly silt, from the vadose zone of borehole cores 299-W11–92 and 299-W15–226. Natural calcium carbonate cementation of the sediment was apparent. Sediment 2: composite from different depths within one well (299-W11–92). Sediment 3: composite of saturated zone sediments of two different wells: 299-W11–92 and 299-W15–226.bTotal dissolved organic carbon is the total organic carbon released from the sediment to the aqueous phase (<0.45 μm) after 21 days of contact during the sediment/groundwater batch iodine uptake experiment.cSuspensions were spiked with either iodide or iodate but during contact period the spiked species transformed to other species. Consequently these are not species-specific Kd values.