Table 2. Variation of Secondary Alcohols Used in Diastereoselective Amination.
Reaction conditions: 0.5 mmol of 1, 0.5 mmol of 2, 1 mol % Ru-Macho, 15 mol % KOH, 0.5 mL of toluene, 120 °C.
Isolated yields.
Determined by 1H NMR analysis.
Determined by polarimetry.