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. Author manuscript; available in PMC: 2015 Oct 11.
Published in final edited form as: Chem Commun (Camb). 2014 Oct 11;50(79):11679–11682. doi: 10.1039/c4cc02969k

Table 2.

Reactivity of Substituted N-Phenylcarbamate Palladacycles toward Ub- Hpga

graphic file with name nihms622754u2.jpg
entry palladacycles conversion (%)b
10 s 3 min
1 graphic file with name nihms622754t9.jpg
9 		83 >99
2 graphic file with name nihms622754t10.jpg
10 		71 >99
3 graphic file with name nihms622754t11.jpg
11 		79 97
4 graphic file with name nihms622754t12.jpg
12 		42 >99
5 graphic file with name nihms622754t13.jpg
13 		40 >99
6 graphic file with name nihms622754t14.jpg
14 		49 >99
7 graphic file with name nihms622754t15.jpg
15 		74 >99
8 graphic file with name nihms622754t16.jpg
16 		80 >99
9 graphic file with name nihms622754t17.jpg
17 		74 >99
10 graphic file with name nihms622754t18.jpg
18 		35 >99
11 graphic file with name nihms622754t19.jpg
19 		41 >99
12 graphic file with name nihms622754t20.jpg
20 		41 53
a

Reaction was carried out by incubating 2.5 μM Ub-Hpg with 10 μM palladacycle at room temperature for the indicated time (see detail procedure in SI, general procedures for the reaction of palladacycles with Ub-Hpg).

b

Conversion was determined based on LC-MS analysis: conversion % = Iproduct/(IUb-Hpg + Iproduct), where IUb-Hpg and Iproduct represent the ion counts of Ub-Hpg and the product, respectively.