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. 2014 Feb 12;9(4):461–473. doi: 10.1002/biot.201300210

Table 2.

Steady-state kinetic parameters of chlorite degradationa)

pH KM (μM) kcat (s–1) kcat/KM (M–1 s–1) E°' (mV) reference
AoCld 7.2b) 170 1200 7.1 × 106 –23 ± 9 [1, 4, 32]
–158 ± 9

5.2c) 620 20000 3.2 × 107
DaCld 6.8d) 212 7500 3.5 × 107 –23 [8, 36, 38]
7.6c) 430 3000 6.9 × 106

IdCld 7.0e) 260 1800 6.9 × 106 –21 [7]

NdCld 7.0f) 69 43.0 6.2 × 105 –113 ± 5 [12, 37]

NwCld 7.0g) 90 190 2.1 × 106 –119 ± 5 [11, 37]

PcCld 6.0h) 84 230 2.7 × 106 [9]

SaHemQ (Cld) 6.8i) NA NA NA [30]

TtCld 7.0j) 13 0.77 59 [34]

DaCld R183A 6.8k) 14600 91 6.2 × 103 –4 [38]

DaCld R183K 6.8k) 42000 1000 2.5 × 104 –18 [38]

DaCld R183Q 6.8k) 50000 350 6.9 × 103 –34 [38]

DaCld W227F 6.0j) 210 1300 6.1 × 106 [35]
8.0j) 620 440 7.1 × 105

DaCld W156F 6.0j) 160 2100 1.3 × 107 [35]
8.0j) 130 470 3.7 × 106

DaCld W155F 6.0j) NA NA NA [35]
8.0j) NA NA NA

NdCld R173A 7.0l) 90 2.8 3.1 × 104 [12]

NdCld R173K 7.0l) 898 14.0 1.5 × 104 [12]
a)

Please note (i) the varying pH-values; (ii) that chlorite dismutases are inactivated during chlorite degradation; and (iii) the different chlorite concentration regimes used in the various laboratories. Additionally, standard reduction potentials of the Fe(III)/Fe(II) couple for some Clds have been published. NA, no activity detected.

b)

[ClO2] up to 15 mM

c)

[ClO2] 0.08–21 mM

d)

[ClO2] 0.08–2 mM

e)

[ClO2] 0.2–1.5 mM

f)

[ClO2] 0.05–80 mM

g)

[ClO2] 0.05–100 mM

h)

[ClO2] 0.001–0.5 mM

i)

[ClO2] up to 20 mM

j)

[ClO2] not reported

k)

[ClO2] 0.08–2 mM

l)

[ClO2] 0.05–80 mM