Table 1. Exponential Fit Lifetimes for Temperature-Jump Data.
probe frequency | experimental relaxation lifetime | simulation relaxation lifetime |
---|---|---|
1710 cm–1 | 69 ± 6 μs | 63.6 ± 0.6 μs |
1704 cm–1 | 33 ± 3 μs (14%)a | 332.0 ± 0.6 μs |
480 ± 20 μs (86%)a | ||
1685 cm–1 | 254 ± 3 μs | 245.6 ± 0.6 μs |
1679 cm–1 | 128 ± 1 μs | 134.0 ± 0.4 μs |
1670 cm–1 | 44.2 ± 0.6 μs | 93.81 ± 0.04 μs |
Percent contribution of the phase to the overall fit.