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. 2014 Aug 22;118(37):10854–10862. doi: 10.1021/jp5050546

Table 1. Exponential Fit Lifetimes for Temperature-Jump Data.

probe frequency experimental relaxation lifetime simulation relaxation lifetime
1710 cm–1 69 ± 6 μs 63.6 ± 0.6 μs
1704 cm–1 33 ± 3 μs (14%)a 332.0 ± 0.6 μs
  480 ± 20 μs (86%)a  
1685 cm–1 254 ± 3 μs 245.6 ± 0.6 μs
1679 cm–1 128 ± 1 μs 134.0 ± 0.4 μs
1670 cm–1 44.2 ± 0.6 μs 93.81 ± 0.04 μs
a

Percent contribution of the phase to the overall fit.