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Peptide induction of anhydrous cholesterol crystallite formation
| TM31C (long peptide) | TM19 (short peptide) | |||||
|---|---|---|---|---|---|---|
| Parameters | 2.5 mol % | 5 mol % | 7.5 mol % | 2.5 mol % | 5 mol % | 7.5 mol % |
| ΔH (cal/mol) | 290 | 623 | 864 | 131 | 149 | 189 |
| Tm (°C) | 38.7 | 36.4 | 35.6 | 37.6 | 38 | 37.8 |
| T1/2 (°C) | 4.4 | 1.9 | 1.8 | 4.2 | 4.1 | 4.2 |
The thermodynamic correspond to the anhydrous cholesterol endothermic phase transition near 36°C.
