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. Author manuscript; available in PMC: 2014 Sep 18.
Published in final edited form as: J Am Chem Soc. 2013 Jul 16;135(30):11299–11308. doi: 10.1021/ja4047872

Figure 2.

Figure 2

a) Temperature dependence of τc for ELPs A-y and A8V2-y. b) The temperature dependence of the isotropic hyperfinecoupling constant (aiso) of the DSA species B for selected two-component spectra. Note that the data of V-80 perfectly overlaps with the data of A2V8-80 below 60°C. The concentration of the ELPs was 1 wt% in all cases and the DSA concentration was 1 mM. c) Fraction of the DSA species A, χA, as a function of temperature for selected two-component spectra for ELPs of varying chain length and hydrophobicity. Error bars stem from uncertainties in the simulations. d) Fraction of the DSA species A, χA, as a function of temperature for selected two-component spectra for ELP A2V8 with varying chain length. Note that the fraction of incorporated spin probes only depends on the organic mass the ELPs provide for interaction with the probes. Therefore, all measurements were performed at 1 wt% ELP concentration. Note that some data points have been omitted for clarity.