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. 2014 Aug 20;10:1942–1950. doi: 10.3762/bjoc.10.202

Table 6.

Relevant torsion angles (°)a for the five-membered furanose ring and the five-membered 1,3-dioxolane ring in compounds 8 and 9.

Ring Torsion angle Compound

8 9

Furanose O4–C1–C2–C3 26.34(16) 17.62(18)
C1–C2–C3–C4 −5.02(16) 3.34(18)
C2–C3–C4–O4 −17.45(15) −23.03(17)
C3–C4–O4–C1 35.47(15) 35.73(16)
C4–O4–C1–C2 −39.06(17) −33.52(17)
1,3-Dioxolane O2–C2–C3–O3 −6.58(16) 3.57(18)
C2–C3–O3–C14 −16.04(16) 11.31(17)
C3–O3–C14–O2 32.66(16) −21.76(17)
O3–C14–O2–C2 −37.19(16) 24.23(17)
C14–O2–C2–C3 26.66(16) −17.24(17)

aStandard deviations in parentheses.