Table 6.
Relevant torsion angles (°)a for the five-membered furanose ring and the five-membered 1,3-dioxolane ring in compounds 8 and 9.
| Ring | Torsion angle | Compound | |
| 8 | 9 | ||
| Furanose | O4–C1–C2–C3 | 26.34(16) | 17.62(18) |
| C1–C2–C3–C4 | −5.02(16) | 3.34(18) | |
| C2–C3–C4–O4 | −17.45(15) | −23.03(17) | |
| C3–C4–O4–C1 | 35.47(15) | 35.73(16) | |
| C4–O4–C1–C2 | −39.06(17) | −33.52(17) | |
| 1,3-Dioxolane | O2–C2–C3–O3 | −6.58(16) | 3.57(18) |
| C2–C3–O3–C14 | −16.04(16) | 11.31(17) | |
| C3–O3–C14–O2 | 32.66(16) | −21.76(17) | |
| O3–C14–O2–C2 | −37.19(16) | 24.23(17) | |
| C14–O2–C2–C3 | 26.66(16) | −17.24(17) | |
aStandard deviations in parentheses.