Figure 8.

Multistate parabolic modeling of ^RPP_n^+•: pseudo-3D representation of the ground and first excited adiabatic state curves with respect to the effective hole coordinate x for n = 2–10. Minima on the curves are shown as black dots, and the bar charts show the hole distributions in the ground (at a minimum) and vertically excited (at the Franck–Condon point) states. Parameters of MPM: Δε/λ = 0 (^HPP_n^+•), Δε/λ = 8.5 (^ROPP_n^+•), Δε/λ = 3.7 (^iAPP_n^+•); in all cases, H_ab/λ = 9. See Figures S26–S28 in the Supporting Information for the corresponding two-dimensional plots.