Table 2.
The estimated values of K1 and K2 of four neutral enantiomers by y-reciprocal methoda
| L-UCAB-CD | L-UCVB-CD | L-UCLB-CD | L-UCILB-CD | L-UCEB-CD | ||
|---|---|---|---|---|---|---|
| THBP | K1 (M−1) | 5,100 | 7,700 | 9,000 | 11,200 | 7,900 |
| K2 (M−1) | 6,200 | 8,500 | 9,200 | 13,900 | 9,000 | |
| TFAE | K1 (M−1) | 5,400 | 13,700 | 27,000 | 26,500 | 28,000 |
| K2 (M−1) | 6,900 | 14,900 | 48,400 | 51,000 | 71,100 | |
| BOH | K1 (M−1) | 3,800 | 4,300 | 4,700 | 8,500 | 9,100 |
| K2 (M−1) | 4,900 | 5,500 | 7,100 | 8,900 | 9,300 | |
| TSO | K1 (M−1) | 18,400 | 18,800 | 19,000 | 21,500 | 24,200 |
| K2 (M−1) | 20,000 | 22,900 | 20,000 | 25,000 | 56,900 | |
The concentration of IL was varied at levels of 1 mM, 3 mM, 5 mM, 7 mM using a fixed concentration of 30 mM TM-β-CD. Other CE conditions are same as described in the experimental section.