Table 2.
Metal | Veg type | Measured Values
|
Market Basket Comparisonc
|
Guidance Value (EC, 2006) | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|
Meana | Min | Mediana | Max | %ND | Min | Media n | 95th pct. | Max | |||
Pb | Fruit | 0.018 | 0.0023b | 0.012 | 0.21 | 46% | <0.005 | <0.005 | 0.009 | 0.04 | 0.1 |
Leafy | 0.099 | 0.010b | 0.059 | 0.59 | 7% | <0.004 | <0.004 | 0.022 | 0.14 | 0.3 | |
Herb | 0.44 | 0.085 | 0.25 | 2.1 | 0% | N/A | N/A | N/A | N/A | N/A | |
Root | 0.20 | 0.014b | 0.089 | 1.9 | 9% | <0.006 | <0.006 | 0.011 | 0.033 | 0.1 | |
| |||||||||||
Cd | Fruit | 0.014 | 0.0021b | 0.0076 | 0.36 | 81% | <0.001 | 0.006 | 0.026 | 0.053 | 0.05 |
Leafy | 0.028 | <0.013 | 0.019 | 0.20 | 40% | 0.002 | 0.039 | 0.21 | 0.52 | 0.2 | |
Herb | 0.023 | <0.029 | 0.015 | 0.060 | 75% | N/A | N/A | N/A | N/A | 0.2 | |
Root | 0.022 | <0.013 | 0.015 | 0.074 | 63% | <0.002 | 0.015 | 0.038 | 0.081 | 0.1 | |
| |||||||||||
Ba | Fruit | 0.24 | 0.028 | 0.11 | 1.5 | 0% | N/A | N/A | N/A | N/A | N/A |
Leafy | 3.7 | 0.37 | 2.4 | 22 | 0% | 0.16 | 0.59 | 3.2 | 3.7 | N/A | |
Herb | 4.7 | 0.54 | 4.4 | 14 | 0% | N/A | N/A | N/A | N/A | N/A | |
Root | 2.5 | 0.32 | 2.3 | 8.9 | 0% | 1.1 | 2.4 | 3.7 | 4.1 | N/A | |
| |||||||||||
Al | Fruit | 0.30 | 0.079 | 0.25 | 1.7 | 0% | N/A | N/A | N/A | N/A | N/A |
Leafy | 2.4 | 0.17 | 1.3 | 17 | 0% | N/A | N/A | N/A | N/A | N/A | |
Herb | 5.2 | 0.88 | 2.9 | 39 | 0% | N/A | N/A | N/A | N/A | N/A | |
Root | 0.89 | 0.36 | 0.64 | 3.6 | 0% | N/A | N/A | N/A | N/A | N/A |
All concentrations are reported in mg kg−1 f.w. Sample sizes for each category: fruit (80), leafy (67), herb (16), and root (32).
Results below the detection limit were considered equal to half the detection limit in determining mean and median values.
Minimum detected concentration. Some samples in which Pb and/or Cd were not detected had a detection limit higher than this concentration. Detection limits ranged up to 0.038 mg kg−1 f.w. for Pb and 0.021 mg kg−1 f.w. for Cd.
Market basket concentrations for Pb and Cd are based on graphite furnace atomic absorption spectroscopy analytical results reported by the US FDA for the Total Diet Study. Results were for 384 fruit, 280 leafy, and 360 root vegetable samples (US FDA, 2010, 2007). We measured market-basket concentrations for Ba in vegetables (6 root and 9 leafy samples) purchased at three markets in the Ithaca, NY, area.