Table 1. Chemical Shifts (ppm) of Assigned Protonsa.
H8/H6 | H5/H2 | H1′ | H2′ | H3′ | H4′ | iminob | aminob | |
G1 | 8.06 | NAc | 5.79 | 4.92 | 4.30 | 4.38 | ||
G2 | 7.52 | NA | 5.93 | 4.74 | 4.61 | 4.51 | 12.84 | 8.45/6.85 |
G3 | 7.17 | NA | 5.77 | 4.54 | 4.39 | 4.49 | 13.25 | 8.36/6.97 |
U4 | 7.72 | 5.08 | 5.56 | 4.44 | 4.61 | 4.46 | 14.39 | NA |
U5 | 7.90 | 5.61 | 5.59 | 4.34 | 4.51 | 13.74 | NA | |
G6 | 7.82 | NA | 5.79 | 4.30 | 4.04 | 4.38 | 12.34 | 8.43/6.56 |
A7 | 8.40 | 8.22 | 6.17 | 4.87 | 4.21 | 4.56 | NA | |
C8 | 7.73 | 5.56 | 5.45 | 4.24 | 3.98 | 4.16 | NA | |
C9 | 7.74 | 5.46 | 5.49 | 4.48 | 4.56 | 4.40 | NA | |
G10 | 7.62 | NA | 5.74 | 4.45 | 4.60 | 4.50 | 12.64 | 8.25/6.71 |
U11 | 7.78 | 5.41 | 5.91 | 4.41 | 4.71 | 4.46 | 14.34 | NA |
U12 | 7.85 | 5.68 | 5.80 | 4.41 | 4.64 | 4.48 | NA | |
G13 | 7.85 | NA | 5.72 | 4.73 | 4.48 | 12.76 | ||
A14 | 7.75 | 7.66 | 5.87 | 4.58 | 4.53 | 4.50 | NA | |
A15 | 7.78 | 7.66 | 5.54 | 4.46 | 4.41 | NA | ||
U16 | 7.53 | 5.47 | 5.61 | 4.12 | 4.29 | 4.61 | NA | |
C17 | 7.74 | 5.98 | 5.95 | 4.36 | 4.66 | 4.53 | NA | |
U18 | 7.85 | 5.88 | 5.82 | 4.23 | 4.50 | 4.58 | 11.53 | NA |
C19 | 7.69 | 5.68 | 5.54 | 4.62 | 4.30 | NA | ||
A20 | 7.95 | 7.22 | 5.84 | 4.55 | 4.45 | 4.48 | NA | |
C21 | 7.39 | 5.20 | 5.20 | 4.39 | 4.31 | 4.47 | NA | |
G22 | 7.38 | NA | 5.64 | 4.42 | 4.62 | 12.52 | 8.13/6.67 | |
G23 | 7.03 | NA | 5.65 | 4.60 | 4.34 | 4.65 | 13.12 | 8.03/6.48 |
C24 | 7.66 | 5.29 | 5.37 | 4.46 | 4.38 | 4.55 | NA | |
A25 | 8.05 | 6.78 | 5.78 | 4.46 | NA | 7.87/6.76 | ||
A26 | 7.94 | 7.71 | 5.90 | 4.40 | 4.35 | 4.42 | NA | 7.70/ |
C27 | 7.51 | 5.17 | 5.37 | 4.35 | 4.00 | 4.16 | NA | |
C28 | 7.75 | 5.41 | 5.51 | 4.24 | 4.00 | 4.34 | NA | |
C29 | 7.66 | 5.46 | 5.73 | 3.98 | 4.19 | 4.16 | NA | 8.30/6.99 |
Assignments of nonexchangeable protons are at 25°C. All chemical shifts are reported relative to TSP.
Assignments of imino and amino protons are at 10°C.
NA: not applicable.