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. 2014 Sep 10;136(38):13194–13197. doi: 10.1021/ja508165a

Table 5. Aromatic C(sp2)–H Alkylationa,b.

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a

Condition A: 0.1 mmol of 1, 2.5 equiv of 2, 10 mol % of Pd(TFA)2, 20 mol % of L13, 2.0 equiv of AgOPiv, 0.5 mL of DCE, 80 °C, under air, 20 h.

b

Isolated yields.

c

1H NMR yield without L13 in parentheses.

d

Condition B: 0.1 mmol of 1, 2.5 equiv of 2, 10 mol % of Pd(OAc)2, 20 mol % of L11, 3.0 equiv of AgOAc, 1.5 mL of DCE, 90 °C, under air, 20 h.

e

Condition A, except using L1 instead of L13.

f

Condition A, except using 3.0 equiv of AgOPiv.